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51.
Richard Dame Norbert Dankers Theo Prins Henk Jongsma Aad Smaal 《Estuaries and Coasts》1991,14(2):130-138
The uptake and release of materials by intertidal mussel beds were directly measured in two cultivated Dutch estuaries. Generally, chlorophylla, seston, and particulate organic carbon were taken up, while ammonium, orthophosphate, and silicate were released. The observed rates were higher than values computed from organismic observations and similar to those observed for intertidal oyster reefs in South Carolina. Specific estuarine material turnover rates varied from 1 week to 38 weeks when calculated with mussel bed fluxes. The fastest turnover rates were for chlorophylla and ammonium. These results support the idea that dense assemblages of bivalves are major components in the recycling of nutrients in estuaries. 相似文献
52.
Charles H. Nelson Douglas S. Hall Francis C. Fekel Robert E. Fried Richard E. Lines Helen C. Lines 《Astrophysics and Space Science》1991,182(1):1-17
Photometry of HD 155638=V792 Her has been analyzed to determine the elements of this totally eclipsing RS CVn binary. The light variation outside eclipse was found to have a period of 27d.07±0d.07, which is slightly different from the 27d.5384±0d.0045 orbital period. Analysis of the eclipses was achieved by a modification of the Russell-Merrill technique. With the aid of radial velocity measures, absolute elements were obtained for the hot and cool stars, respectively;R
h=2.58R
,R
c=12.28R
,M
h=1.40M
,M
c=1.46M
,i=80o.61 and velocity semi-amplitudesK
c=48.36 km s–1±0.79 km s–1, andK
h=50.50 km s–1±0.33 km s–1. The apparent magnitudes areV
h=9
m
.73 andV
c=8
m
.48. The distance to HD 155638 was estimated to be 310 parsecs. 相似文献
53.
Combined fluid inclusion microthermometry and microanalysis by laser ablation inductively coupled plasma mass spectrometry
(LA-ICPMS) are used to constrain the hydrothermal processes forming a typical Climax-type porphyry Mo deposit. Molybdenum
mineralisation at Questa occurred in two superimposed hydrothermal stages, a magmatic-hydrothermal breccia and later stockwork
veining. In both stages, texturally earliest fluids were single-phase, of low salinity (~7 wt.% NaClequiv.) and intermediate-density. Upon decompression to ~300 bar, they boiled off a vapour phase, leaving behind a residual brine
(up to 45 wt.% NaClequiv) at temperatures of ~420°C. The highest average Mo concentrations in this hot brine were ~500 μg/g, exceeding the Mo content
of the intermediate-density input fluid by about an order of magnitude and reflecting pre-concentration of Mo by fluid phase
separation prior to MoS2 deposition from the brine. Molybdenum concentrations in brine inclusions, then, decrease down to 5 μg/g, recording Mo precipitation
in response to cooling of the saline liquid to ~360°C. Molybdenite precipitation from a dense, residual and probably sulphide-depleted
brine is proposed to explain the tabular shape of the ore body and the absence of Cu-Fe sulphides in contrast to the more
common Cu-Mo deposits related to porphyry stocks. Cesium and Rb concentrations in the single-phase fluids of the breccia range
from 2 to 8 and from 40 to 65 μg/g, respectively. In the stockwork veins, Cs and Rb concentrations are significantly higher
(45–90 and 110–230 μg/g, respectively). Because Cs and Rb are incompatible and hydrothermally non-reactive elements, the systematic
increase in their concentration requires two distinct pulses of fluid exsolution from a progressively more fractionated magma.
By contrast, major element and ore metal concentrations of these two fluid pulses remain essentially constant. Mass balance
calculations using fluid chemical data from LA-ICPMS suggest that at least 25 km3 of melt and 7 Gt of deep input fluid were necessary to provide the amount of Mo contained in the stockwork vein stage alone.
While the absolute amounts of fluid and melt are uncertain, the well-constrained element ratios in the fluids together with
empirical fluid/melt partition coefficients derived from the inclusion analyses suggest a high water content of the source
melt of ~10%. In line with other circumstantial evidence, these results suggest that initial fluid exsolution may have occurred
at a confining pressure exceeding 5 kbar. The source of the molybdenum-mineralising fluids probably was a particularly large
magma chamber that crystallised and fractionated in the lower crust or at mid-crustal level, well below the shallow intrusions
immediately underlying Questa and other porphyry molybdenum deposits.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
54.
Jaap S. Sinninghe Damst Marcel M.M. Kuypers Richard D. Pancost Stefan Schouten 《Organic Geochemistry》2008,39(12):1703
The stable carbon isotopic compositions of free and sulfur (S)-bound biomarkers derived from algae, (cyano)bacteria, archaea and higher plants and total organic carbon (TOC) during the first phase of the late Cenomanian/Turonian oceanic anoxic event (OAE) were measured in black shales deposited in the southern proto-Atlantic Ocean in the Cape Verde basin (DSDP Site 367) to determine the response of these organisms to this major perturbation of the global carbon cycle resulting from widespread burial of marine organic matter. The average positive isotope excursions of TOC and biomarkers varied from 5.1‰ to 8.3‰. The δ13C values were cross correlated to infer potential common sources of biomarkers. This revealed common sources for C31 and C32 hopanes but no 1:1 relationship for pristane and phytane. The correlation of δ13CTOC with the δ13C value of sulfur (S)-bound phytane is the strongest. This is because S-bound phytane is derived from phytol that originates from all marine primary producers (algae and cyanobacteria) and thus represents a weighted average of their carbon isotopic compositions. The δ13C values of S-bound phytane and C35 hopane were also used to estimate pCO2 levels. Before the OAE burial event, pCO2 levels are estimated to be ca. 1300 ppmv using both biomarkers and the independent maximum Rubisco fractionation factors. At times of maximum organic carbon burial rates during the OAE, reconstructed pCO2 levels are estimated to be ca. 700 ppmv. However, compared to other C/T OAE sections the positive isotope excursion of S-bound phytane is also affected by an increased production during the OAE. When we compensate for this, we arrive at pCO2 levels around 1000 ppmv, a reduction of ca. 25%. This indicates that burial of organic matter can have a large effect on atmospheric CO2 levels. 相似文献
55.
Supercritical gas sorption on moist coals 总被引:2,自引:1,他引:1
The effect of moisture on the CO2 and CH4 sorption capacity of three bituminous coals from Australia and China was investigated at 55 °C and at pressures up to 20 MPa. A gravimetric apparatus was used to measure the gas adsorption isotherms of coal with moisture contents ranging from 0 to about 8%. A modified Dubinin–Radushkevich (DR) adsorption model was found to fit the experimental data under all conditions. Moisture adsorption isotherms of these coals were measured at 21 °C. The Guggenheim–Anderson–de Boer (GAB) model was capable of accurately representing the moisture isotherms over the full range of relative pressures.Moist coal had a significantly lower maximum sorption capacity for both CO2 and CH4 than dry coal. However, the extent to which the capacity was reduced was dependent upon the rank of the coal. Higher rank coals were less affected by the presence of moisture than low rank coals. All coals exhibited a certain moisture content beyond which further moisture did not affect the sorption capacity. This limiting moisture content was dependent on the rank of the coal and the sorbate gas and, for these coals, corresponded approximately to the equilibrium moisture content that would be attained by exposing the coal to about 40–80% relative humidity. The experimental results indicate that the loss of sorption capacity by the coal in the presence of water can be simply explained by volumetric displacement of the CO2 and CH4 by the water. Below the limiting moisture content, the CO2 sorption capacity reduced by about 7.3 kg t− 1 for each 1% increase in moisture. For CH4, sorption capacity was reduced by about 1.8 kg t− 1 for each 1% increase in moisture.The heat of sorption calculated from the DR model decreased slightly on addition of moisture. One explanation is that water is preferentially attracted to high energy adsorption sites (that have high energy by virtue of their electrostatic nature), expelling CO2 and CH4 molecules. 相似文献
56.
This paper presents results of a small scale study that utilized particle-tracking techniques to evaluate transport of river
water through an alluvial aquifer in a bank infiltration testing site in El Paso, Texas, USA. The particle-tracking survey
was used to better define filtration parameters. Several simulations were generated to allow visualization of the effects
of well placement and pumping rate on flow paths, travel time, the size of the pumping influence zone, and proportion of river-derived
water and groundwater mixing in the pumping well. Simulations indicate that migration of river water into the aquifer is generally
slow. Most water does not arrive at the well by the end of an 18-day pumping period at 0.54 m3/min pumping rate for a well located 18 m from the river. Forty-four percent of the water pumped from the well was river water.
The models provided important information needed to design appropriate sampling schedules for bank filtration practices and
ensured meeting adequate soil-retention times. The pumping rate has more effect on river water travel time than the location
of the pumping well from the river. The examples presented in this paper indicate that operating the pumping well at a doubled
distance from the river increased the time required for the water to travel to the well, but did not greatly change the capture
zone. 相似文献
57.
Thomas B. Boving Mark H. Stolt Janelle Augenstern Brian Brosnan 《Environmental Geology》2008,55(3):571-582
The control of polluted surface runoff and the assessment of possible impacts on groundwater is a concern at the local and
regional scale. On this background, a study investigates possible impacts of organic and inorganic pollutants (including bacteria)
originating from a permeable asphalt parking lot on the water quality immediately beneath it. The functioning of the permeable
pavement, including clogging and restricted vertical percolation, was also evaluated. Four nested sample ports (shallow and
deep) were installed below low- and high-traffic areas, including one port outside the parking lot. At least initially there
was a good hydraulic connection between the parking surface and the shallow sample ports. The presence of a geotextile layer
at the base of the parking lot structure, however, was identified in lab tests as one factor restricting vertical percolation
to the deeper ports. Clogging of the permeable surface was most pronounced in heavy traffic areas and below snow pile storage
areas. Corroborated by high electric conductivity and chloride measurements, sand brought in by cars during winter was the
principal cause for clogging. No bacteria or BOD were found in percolating water. Polycyclic aromatic hydrocarbons (PAH) were
present at concentrations near minimum detection limit. Nutrients (nitrate and phosphate) were being leached into the ground
via the permeable parking lot surface at annual flux rates of 0.45–0.84 g/m2/year. A multi-species tracer test demonstrated a retention capacity of the permeable parking lot structure of >90% for metals
and 27% for nutrients, respectively. 相似文献
58.
Geneviève Bordeleau Richard Martel Dirk Schäfer Guy Ampleman Sonia Thiboutot 《Environmental Geology》2008,55(2):385-396
Numerical modelling was done at the Cold Lake Air Weapons Range, Canada, to test whether the dissolved RDX and nitrate detected
in groundwater come from the same sources, and to predict whether contamination poses a threat to the surface water receptors
near the site. Military live fire training activities may indeed pose a risk of contamination to groundwater resources, however
field investigations on military bases are quite recent, and little information is available on the long-term behaviour of
munition residues related contaminants. Very limited information was available about the contaminant source zones, which were
assigned based on our knowledge of current training activities. The RDX plume was well represented with the model, but the
heterogeneous distribution of nitrate concentrations was more difficult to reproduce. It was nonetheless determined that both
contaminants originate from the same areas. According to the model, both contaminants should reach the nearby river, but concentrations
in the river should remain very low if the source zone concentration does not change. Finally, the model allowed the recommendation
of a new location for the main bombing target, which would offer added protection to the river and the lake into which it
flows. 相似文献
59.
Helmut Kerndorff Stephan Kühn Thomas Minden Dagmar Orlikowski Thomas Struppe 《Environmental Geology》2008,55(2):291-301
The aim of this research project is to identify, characterize and quantify natural attenuation (NA) processes in groundwater
affected by emissions of abandoned waste disposal sites in Berlin-Kladow/Gatow, Germany. It is part of the funding priority
called KORA established by the Federal Ministry for Education and Research (BMBF) to explore the extent to which NA can be
used for remedial purposes for varied forms of soil and groundwater contamination. Information on the emission behaviour of
individual parameters is generated on the basis of hydrogeochemical comparison of 20 years old and new data. Using groundwater-modelling
and CFC-analysis, information on the transport and retention of pollutants in groundwater is compiled. The microbial colonization
of contaminated aquifers is characterized by molecular biological methods [polymerase chain reaction (PCR) and denaturing
gradient gel electrophoresis (DGGE)] to differentiate between contaminated and not contaminated zones. 相似文献
60.
V. B. Naumov V. S. Kamenetsky R. Thomas N. N. Kononkova B. N. Ryzhenko 《Geochemistry International》2008,46(6):554-564
Melt inclusions were studied in chrome diopside from the Inagli deposit of gemstones in the Inagli massif of alkaline ultrabasic rocks of potassic affinity in the northwestern Aldan shield, Yakutia, Russia. The chrome diopside is highly transparent and has an intense green color. Its Cr2O3 content varies from 0.13 to 0.75 wt %. Primary and primary-secondary polyphase inclusions in chrome diopside are dominated by crystal phases (80–90 vol %) and contain aqueous solution and a gas phase. Using electron microprobe analysis and Raman spectroscopy, the following crystalline phases were identified. Silicate minerals are represented by potassium feldspar, pectolite [NaCa2Si3O8(OH)], and phlogopite. The most abundant minerals in the majority of inclusions are sulfates: glaserite (aphthitalite) [K3Na(SO4)2], glauberite [Na2Ca(SO4)2], aluminum sulfate, anhydrite (CaSO4), gypsum (CaSO4 × 2H2O), barite (BaSO4), bloedite [Na2Mg(SO4)2 × 4H2O], thenardite (NaSO4), polyhalite [K2Ca2Mg(SO4)4 × 2H2O], arcanite (K2SO4), and celestite (SrSO4). In addition, apatite was detected in some inclusions. Chlorides are probably present among small crystalline phases, because some analyses of aggregates of silicate and sulfate minerals showed up to 0.19–10.3 wt % Cl. Hydrogen was identified in the gas phase of polyphase inclusions by Raman spectroscopy. The composition of melt from which the chrome diopside crystallized was calculated on the basis of the investigation of silicate melt inclusions. This melt contains 53.5 wt % SiO2, considerable amounts of CaO (16.3 wt %), K2O (7.9 wt %), Na2O (3.5 wt %), and SO3 (1.4 wt %) and moderate amounts of Al2O3 (7.5 wt %), MgO (5.8 wt %), FeO (1.1 wt %), and H2O (0.75 wt %). The content of Cr2O3 in the melt was 0.13 wt %. Many inclusions were homogenized at 770–850°C, when all of the crystals and the gas phase were dissolved. The material of inclusions heated up to the homogenization temperature became heterogeneous even during very fast quenching (two seconds) producing numerous small crystals. This fact implies that most of the inclusions contained a salt (rather than silicate) melt of sulfate-dominated composition. Such inclusions were formed from salt globules (with a density of about 2.5 g/cm3) occurring as an emulsion in the denser (2.6 g/cm3) silicate melt from which the chrome diopside crystallized. 相似文献